At present, there are serious problems such as soil impoverishment and heavy metal pollution in Guangxi manganese reclamation area, which have a serious impact on the life and property safety of local residents and agricultural development in mining area. Therefore, taking the reclaimed soil of manganese ore area as the research object, the improvement effect of applying different legume green fertilizer plants to the reclaimed soil of manganese ore area was explored. A total of twelve treatments were set up, which were: CK, TJ, CMX, ZY, ZHT, JK, SDW, JM, JSY, MY, ZS and XG. The results showed that: (1) the contents of available phosphorus, available potassium, total nitrogen and total carbon in the reclaimed soil increased significantly, but the soil pH and organic matter did not change significantly. Compared with CK, the soil available phosphorus content of SDW increased by 200%, and the soil total nitrogen content of MY increased by 126%. (2) The inorganic nitrogen content of the reclaimed soil in the manganese ore area was significantly increased. Compared with CK, the nitrate nitrogen content of ZY soil was increased by 377%, and the ammonium nitrogen content of XG soil was increased by 88.8%; (3) The soil enzyme activities of reclaimed soil in manganese ore area were significantly increased. Compared with CK, the soil nitrogenase activities of ZS, ZHT and ZY were increased by 221%, 202% and 195%. The study shows that leguminous green fertilizer plants have good improvement effect on the soil reclamation in manganese ore area.